Supramolecular chirality induced by a weak thermal force.
نویسندگان
چکیده
We show that the unexpected chirality of aggregated structures based on an uncharged achiral porphyrin system originates from small temperature gradients that act as an asymmetrical physical perturbation; the consequent thermal force gives rise to the thermophoretic motion of the aggregates. We establish that the induced optical activity can be controlled, and even vanished, by minimizing the thermal force.
منابع مشابه
Interfacial assemblies of atypical amphiphilic porphyrins: hydrophobicity/hydrophilicity of substituents, annealing effects, and supramolecular chirality.
Interfacial molecular assemblies of eight atypical amphiphilic porphyrins, substituted with hydrophobic or hydrophilic substituents but without long alkyl chains on their molecular skeletons, have been investigated in terms of supramolecular chiralty generation and amplification. It is found that all of the originally organized interfacial molecular assemblies display very weak or undetectable ...
متن کاملSupramolecular chirality in crystalline assemblies of bile acids and their derivatives; three-axial, tilt, helical, and bundle chirality.
Steroidal bile acids and their derivatives exhibit characteristic inclusion behaviors in the crystalline state. Their crystals present varied assemblies due to asymmetric molecular structures, which relate to supramolecular properties through cooperative weak interactions. An overview indicates that the steroidal assemblies lie in an intermediate position among various molecules and have hierar...
متن کاملSelf-selecting homochiral quadruple-stranded helicates and control of supramolecular chirality.
Enantiomeric M4L4 helical cages have been prepared whose supramolecular chirality is induced by the chemical chirality of the self-sorting amino acid-derived ligands that are used. Using scrambled diastereomeric ligands or achiral glycine-derived ligands yields analogous complexes yet 'turns off' the supramolecular chirality by producing centrosymmetric cages.
متن کاملConstruction of Supramolecular Nanostructures from V-Shaped Amphiphilic Rod-Coil Molecules Incorporating Phenazine Units
A series of bent-shaped molecules, consisting of dibenzo[a,c]phenazine and phenyl groups connected together as a rod segment, and poly(ethylene oxide) (PEO) with a degree of polymerization (DP) of 6 as the coil segment, were synthesized. The self-assembling behavior of these molecules by differential scanning calorimetry (DSC), thermal optical polarized microscopy (POM), small-angle X-ray scatt...
متن کاملWeak Force Measurement in Bistable Optomechanical System
One of the main milestones in the study of opto-mechanical system is to increase the sensitivity of weak forces measurement up to the standard quantum limit. We have studied the detection of weak force under a bistable condition in red detuned regime. In this case, dynamics of the system behaves asymptotically similar to stationary state and applying external force affects phase and fluctuation...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Soft matter
دوره 10 1 شماره
صفحات -
تاریخ انتشار 2014